Capacity-Equivocation Regions of the DMBCs with Noiseless Feedback

The discrete memoryless broadcast channels (DMBCs) with noiseless feedback are studied. The entire capacity-equivocation regions of two models of the DMBCs with noiseless feedback are obtained. One is the degraded DMBCs with rate-limited feedback; the other is the less and reversely less noisy DMBCs with causal feedback. In both models, two kinds of messages are transmitted. The common message is to be decoded by both the legitimate receiver and the eavesdropper, while the confidential message is only for the legitimate receiver. Our results generalize the secrecy capacity of the degraded wiretap channel with rate-limited feedback (Ardestanizadeh et al., 2009) and the restricted wiretap channel with noiseless feedback (Dai et al., 2012). Furthermore, we use a simpler and more intuitive deduction to get the single-letter characterization of the capacity-equivocation region, instead of relying on the recursive argument which is complex and not intuitive

Interpretation and prediction of optical properties: novel fluorescent dyes as a test case

The rapid development of modern quantum mechanical theories and computational resources facilitates extended characterization of molecular systems of increasing size and complexity, including chromophores of biochemical or technological interest. Efficient and accurate computations of molecular structure and properties in the ground and excited electronic states are routinely performed using density functional theory (DFT) and its time-dependent (TD-DFT) counterpart. However, the direct comparison with experiment requires simulation of electronic absorption or emission spectra, for which inclusion of vibrational effects leads to more realistic line shapes while at the same time allowing for more reliable interpretation and prediction of optical properties and providing additional information that is not available from experimental low-resolution UV-vis spectra. Computational support can help identify the most interesting chromophores among a large number of potential candidates for designing new materials or sensors, as well as unraveling effects contributing to the overall spectroscopic phenomena. In this perspective, recently developed viologen derivatives (1,1′-disubstituted-4,4′-bipyridyl cation salts, viol) are selected as test cases to illustrate the advantages of spectroscopic theoretical methodologies, which are still not widely used in “chemical” interpretation. Although these molecules are characterized by improved stability as well as the dual function of chromism and luminescence, their detailed spectroscopic characterization is hampered due to the availability of only low-resolution experimental spectra. DFT-based absorption and emission spectra are exploited in the analysis of optical properties, allowing detailed investigation of vibrational effects and gaining more insights on the structure–spectra relationship, which can be extended to develop further viologen dyes with improved optical properties

In Situ TEM Study of the Degradation of PbSe Nanocrystals in Air

PbSe nanocrystals have attracted widespread attention due to a variety of potential applications. However, the practical utility of these nanocrystals has been hindered by their poor air stability, which induces undesired changes in the optical and electronic properties. An understanding of the degradation of PbSe nanocrystals when they are exposed to air is critical for improving the stability and enhancing their applications. Here, we use in situ transmission electron microscopy (TEM) with an environmental cell connected to air to study PbSe nanocrystal degradation triggered by air exposure. We have also conducted a series of complementary studies, including in situ environmental TEM study of PbSe nanocrystals exposed to pure oxygen and PbSe nanocrystals in H2O using a liquid cell, and ex situ experiments, such as O2 plasma treatment and thermal heating of PbSe nanocrystals under different air exposure. Our in situ observations reveal that when PbSe nanocrystals are exposed to air (or oxygen) under electron beam irradiation, they experience a series of changes, including shape evolution of individual nanocrystals with the cuboid intermediates, coalescence between nanocrystals, and formation of PbSe thin films through drastic solid-state fusion. Further studies show that the PbSe thin films transform into an amorphous Pb rich phase or eventually pure Pb, which suggest that Se reacts with oxygen and can be evaporated under electron beam illumination. These various in situ and ex situ experimental results indicate that PbSe nanocrystal degradation in air is initiated by the dissociation and removal of ligands from the PbSe nanocrystal surface

Wiretap Channel with Information Embedding on Actions

Information embedding on actions is a new channel model in which a specific decoder is used to observe the actions taken by the encoder and retrieve part of the message intended for the receiver. We revisit this model and consider a different scenario where a secrecy constraint is imposed. By adding a wiretapper in the model, we aim to send the confidential message to the receiver and keep it secret from the wiretapper as much as possible. We characterize the inner and outer bounds on the capacity-equivocation region of such a channel with noncausal (and causal) channel state information. Furthermore, the lower and upper bounds on the sum secrecy capacity are also obtained. Besides, by eliminating the specific decoder, we get a new outer bound on the capacity-equivocation region of the wiretap channel with action-dependent states and prove it is tighter than the existing outer bound. A binary example is presented to illustrate the tradeoff between the sum secrecy rate and the information embedding rate under the secrecy constraint. We find that the secrecy constraint and the communication requirements of information embedding have a negative impact on improving the secrecy transmission rate of the given communication link

Wiretap Channel with Action-Dependent States and Rate-Limited Feedback

We introduce the wiretap channel with action-dependent states and rate-limited feedback. In the new model, the state sequence is dependent on the action sequence which is selected according to the message, and a secure rate-limited feedback link is shared between the transmitter and the receiver. We obtain the capacity-equivocation region and secrecy capacity of such a channel both for the case where the channel inputs depend noncausally on the state sequence and the case where they are restricted to causal dependence. We construct the capacity-achieving coding schemes utilizing Wyner's random binning, Gel'fand and Pinsker’s coding technique, and rate splitting. Furthermore, we compare our results with the existing approaches without feedback, with noiseless feedback, and without action-dependent states. The simulation results show that the secrecy capacity of our model is bigger than that of the first two existed approaches. Besides, it is also shown that, by taking actions to affect the channel states, we guarantee the data integrity of the message transmitted in the two-stage communication systems although the tolerable overhead of transmission time is brought

Research Progress on Polymer Solar Cells Based on PEDOT:PSS Electrodes

Solution-processed polymer solar cells (PSCs) have attracted dramatically increasing attention over the past few decades owing to their advantages of low cost, solution processability, light weight, and excellent flexibility. Recent progress in materials synthesis and devices engineering has boosted the power conversion efficiency (PCE) of single-junction PSCs over 17%. As an emerging technology, it is still a challenge to prepare solution-processed flexible electrodes for attractive flexible PSCs. Poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) is one of the most promising candidates for electrodes due to its high conductivity (>4000 S/cm), excellent transmittance (>90%), intrinsically high work function (WF > 5.0 eV), and aqueous solution processability. To date, a great number of single-junction PSCs based on PEDOT:PSS electrodes have realized a PCE over 12%. In this review, we introduce the current research on the conductive complex PEDOT:PSS as well as trace the development of PEDOT:PSS used in electrodes for high performance PSCs and perovskite solar cells. We also discuss and comment on the aspects of conductivity, transmittance, work-function adjustment, film preparing methods, and device fabrications. A perspective on the challenges and future directions in this field is be offered finally

Performance Comparison of Advanced Transcritical Power Cycles with High-Temperature Working Fluids for the Engine Waste Heat Recovery

To efficiently recover the waste heat of mobile engine, two advanced transcritical power cycles, namely split cycle and dual pressure cycle, are employed, based on the recuperative cycle. Performances of the two cycles are analyzed and compared through the development of thermodynamic models. Under given gas conditions, seven high-temperature working fluids, namely propane, butane, isobutane, pentane, isopentane, neopentane, and cyclopentane, are selected for the two cycles. At the design system parameters, the highest work 48.71 kW, is obtained by the split cycle with butane. For most of fluids, the split cycle has a higher work than the dual pressure cycle. Furthermore, with the increase of turbine inlet pressure, net work of the split cycle goes up firstly and then decreases, while the work of dual pressure cycle increases slowly. For the split cycle, there exists a split ratio to get the maximum network. However, for the dual pressure cycle, the larger the evaporation temperature, the higher the net work. On this basis, system parameters are optimized by genetic algorithm to maximize net work. The results indicate that the highest work 49.96 kW of split cycle is obtained by pentane. For the considered fluids, except cyclopentane, split cycle always has a higher work than dual pressure cycle. Due to the higher net work and fewer system components, split cycle is recommended for the engine waste heat recovery

Effects of Concurrent Strength and HIIT-Based Endurance Training on Physical Fitness in Trained Team Sports Players: A Systematic Review and Meta-Analysis

Background: Concurrent strength and HIIT-based endurance training (CT) has merit in time-saving in team sports. However, the effect of CT on physical fitness remained equivocal. This meta-analysis aimed to determine whether CT would produce an interference effect on the development of physical fitness when compared to strength training (ST) or HIIT-based endurance training (HET) alone in trained team sports players. Methods: A total of 2478 studies from three databases were screened. 52 full texts were reviewed. Seven studies were finally included and then subgroups were used for quantitative analysis. Results: Compared to ST alone, CT had a significant effect on the development of maximal lower-body strength in trained team sports players (MD 4.20 kg, 95% CI 0.71–7.68, p = 0.02, I2 = 20%), but there was no significant difference between the groups on training adaptation in lower-body power (SMD 0.08, 95% CI −0.23–0.39, p = 0.62, I2 = 26%). Furthermore, a sub-group analysis based on the internal organization order of CT revealed that there was no statistically significant subgroup effect between CT and ST alone in all parameters. Conclusions: Well-designed CT regimens did not interfere with the development of physical fitness of trained team sports players

Possible Causes of Discordance in Refraction in Monozygotic Twins: Nearwork, Time Outdoors and Stochastic Variation

Purpose: To evaluate the impact of differences in nearwork and time spent outdoors on difference in refraction in monozygotic (MZ) twins. Methods: Data on MZ twins aged 7 to 18 years from the Guangzhou Twin Eye Study were used in this analysis. A standard questionnaire was administered by personal interview to estimate time spent on nearwork and time spent outdoors. Spherical equivalent (SE) was measured by autorefraction under cycloplegia. The interaction between age and nearwork or time spent outdoors was also estimated. Results: A total of 490 MZ twin pairs (233 male and 257 female) were eligible in this analysis, the mean age was 13.14 ± 2.49. In the mixed-effects model, nearwork difference was a risk factor of discordance in myopic SE (β = −0.11 diopter (D)/h, P = 0.009), the overall association between time outdoors difference and SE discordance was not significant (β = −0.89 (D)/h, P = 0.120) although an interaction between time spent outdoors difference and age was detected (β = 0.07 (D)/h, P = 0.002). Furthermore, difference in nearwork and time outdoors explained about 1.8% and 2.5% of the variation in SE discordance, respectively. Conclusions: Given the very marked genetic similarity of MZ twins, and the small effects of known risk factors on SE discordance, we suggest that the SE discordance across MZ twins largely results from stochastic variations at the genomic or epigenetic levels, or from uncollected environmental factors. METHODS: Data on MZ twins aged 7 to 18 years from the Guangzhou Twin Eye Study were used in this analysis. A standard questionnaire was administered by personal interview to estimate time spent on nearwork and time spent outdoors. Spherical equivalent (SE) was measured by autorefraction under cycloplegia. The interaction between age and nearwork or time spent outdoors was also estimated. RESULTS: A total of 490 MZ twin pairs (233 male and 257 female) were eligible in this analysis, the mean age was 13.14 ± 2.49. In the mixed-effects model, nearwork difference was a risk factor of discordance in myopic SE (β = -0.11 diopter (D)/h, P = 0.009), the overall association between time outdoors difference and SE discordance was not significant (β = -0.89 (D)/h, P = 0.120) although an interaction between time spent outdoors difference and age was detected (β = 0.07 (D)/h, P = 0.002). Furthermore, difference in nearwork and time outdoors explained about 1.8% and 2.5% of the variation in SE discordance, respectively. CONCLUSIONS: Given the very marked genetic similarity of MZ twins, and the small effects of known risk factors on SE discordance, we suggest that the SE discordance across MZ twins largely results from stochastic variations at the genomic or epigenetic levels, or from uncollected environmental factors.Supported by the National Natural Science Foundation of China (81125007) and Fundamental Research Funds of the State Key Laboratory, the University of Melbourne Research Accelerator Program and the CERA Foundation (MH). The Centre for Eye Research Australia receives Operational Infrastructure Support from the Victorian State Governmen